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TOXICS RELEASE INVENTORY

Table 2-1: Nitric Acid Concentration Versus pH ..... 4 Table 2-2: Nitric Acid Treatment Efficiencies for Various pH Changes..... 6 Table 3-1: Listing by CAS Number of Some of the Individual Chemicals within the Water Dissociable ... If the nitric acid treatment efficiency is not equal to 100 percent (pH is less than 6.0), the amount of the

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Nitrocellulose | SpringerLink

When the concentration of nitric acid is 60–65%, the cellulose can be swollen, and small molecular compounds can be formed; when the concentration of nitric acid is 70–75%, the cellulose can be partially dissolved; when the concentration of nitric acid reaches 78–85%, the cellulose is completely dissolved and forms cellulose nitrate.

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Up to 75 tonne per day Nitric Acid Concentration Plant

By using water a 50% nitric acid will be obtained under pressure. The existing exhaust gas contains 200 ppm NOx. Process Description acc. to Flow Sheet J 875-110 and P+I-Diagram J 875-120, 121 The plant is designed to produce high concentrated nitric acid out of weak nitric acid and can be divided into three sections - Nitric Acid Concentration

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Nitric Acid | NIOSH | CDC

CAS No. . Nitric acid (HNO₃) is a colorless liquid with yellow or red fumes with an acrid odor. Exposure to nitric acid can cause irritation to the eyes, skin, and mucous membrane; it can also cause delayed pulmonary edema, pneumonitis, bronchitis, and dental erosion. Nitric acid is highly corrosive. Workers may be harmed from ...

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Nitrogen Tetroxide

An aqueous solution of (typically) 55%–65% (v/v) nitric acid is withdrawn from the bottom of the tower; the acid concentration can vary from 30% to 70% (v/v) nitric acid. However, the acid concentration depends upon the temperature, pressure, and number of absorption stages as well as on the concentration of nitrogen oxides entering the …

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Formation and control of N2O in nitric acid production: …

As base case a nitric acid plant with a production capacity of 1500 t nitric acid (as 100 wt.%) per day, a tail-gas flow of 200,000 Nm 3 h −1 and a N 2 O concentration of 1500 ppmv in the tail-gas has been used. A distinction is made between new and existing nitric acid plants.

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Full article: Effect of nitrate on corrosion of austenitic stainless

The 1 M nitric acid concentration was established with respect to the literature value of 0.8 M reported for the uranium concentration in the Rokkasho reprocessing plant [Citation 2]. The nitrates concentration was adjusted so as to equalize total NO 3 − concentration in the test solutions.

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Ensuring Munitions Readiness through Industrial Base …

(NAC/SAC) plant at Holston Army Ammunition Plant will process spent nitric acid from the Insensitive Munition Explosive (IMX) production processes and purify and recycle concentrated...

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Nitric Acid

Plants can be designed for applications in fertilizer or explosives industries (usually approx. 60% nitric acid concentration), or for the chemical industry (up to 68% nitric acid concentration, azeotropic acid). Technology Highlights: More than 130 references for all process variants since 1958, 23 references in the 21 st century

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3.2 N2O Adipic Acid Nitric Acid Production 20020116

Kingdom. Most of these countries have only one adipic acid plant. Nitric acid is used primarily to make synthetic commercial fertiliser. Worldwide, the number of nitric acid plants is somewhat uncertain. Estimates range from 255 to 600 plants (Choe et al., 1993; Bockman and Granli, 1994). In 1990, adipic acid production was the largest

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NOx-Waste Gas Treatment | De Dietrich Process Systems

The generated nitric acid leaving the column at the bottom has a concentration of about 50-65wt%. The vent gas leaving the column at the top meets the specification of TA-Luft or even lower. Process Flow Chart of QVF® NOx-Pressure absorption to produce nitric acid

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The Manufacture of Nitric Acid

It is now estimated that the total world output of nitric acid has risen from about 18.3 million tonnes (100 per cent HNO 3) in 1962–63 to just under 23.5 million tonnes in 1965–66 . At this level of production the world's nitric acid plants are believed to operate at an average of 82 per cent of all available production capacity.

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Process Intensification in Nitric Acid Plants by Catalytic Oxidation …

We have evaluated the kinetics of the catalytic oxidation of NO to NO2 using a Pt/alumina catalyst, under conditions relevant to industrial nitric acid production: NO and steam contents up to 5% and 20%, respectively, with temperatures from 250 to 350 °C, and pressures up to 4.7 bar. The objective is to replace the current homogeneous oxidation …

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Economic Impact Analysis for the Nitric Acid Manufacturing …

nitric acid and tends to range from a 50% to 70% concentration of nitric acid in water (Dow, 2008). Fuming or concentrated nitric acid ranges from 85% to in concentration (Dow, 2008). 2.1.3 Materials and Costs of Production Ammonia is the chief raw material required for nitric acid production, and many nitric

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The Complete Aqueous Nitric Acid Solutions Density-Concentration …

Input a temperature and density within the range of the table to calculate for concentration or input concentration to calculate for density. The table below gives the density (kg/L) and the corresponding concentration (% weight) of Nitric Acid (HNO 3) solutions in water at different temperatures in degrees centigrade (°C). The table was taken ...

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Nitric Acid Concentration Plant

Nitric acid is widely used in manufacture of fertilizers, dyes, pharmaceuticals, ammonium nitrate, and other speciality organic nitro-derivatives. In most applications, nitric acid is required in the concentrated form. The process of concentration of nitric acid involved pre-concentration of the acid by conventional method up to a concentration ...

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BASF: The right choice for nitric acid plants

Nitric Acid Production Nitric acid plants are often part of a larger production facility, such as fertilizer or explosives manufacturing. This creates significantly different operational environments. Diluted HNO 3 with a concentration range from 30–70% is produced via ammonia oxidation, nitric oxide oxidation, and absorption, as shown in ...

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Nitric Acid Market Size, Growth | Global Research Report [2030]

The global nitric acid market size was valued at USD 22.92 billion in 2022 and is projected to grow from USD 23.73 billion in 2023 to USD 30.39 billion by 2030, exhibiting a CAGR of 3.6% during the forecast period. Nitric acid (HNO3), also known as aqua fortis, is a colorless compound that turns yellow over a period of time due to the ...

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Nitric Acid

Fax: +27 (0) 11 788 5092. South African Retail Queries: Telephone: +27 (0) 860 335 444. Email: queries&enquiries@. Investor Relations: Telephone: +27 (0) 11 441 3113. Email: investor.relations@. Get Connected. Nitric Acid is a clear, colourless to light yellow liquid with a sweet to acrid, choking odor.

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DENITRATION OF NITRIC ACID SOLUTIONS BY FORMIC …

to reduce the nitric acid concentration of solutions in an evaporator to <1M by metering in formic acid. The formic acid reacts with the nitric acid to form gases (NO, N0 2, C0 2) and water. No cations are added to the system, none of the products of the reaction are solids, and no explosive nitrate compounds can be formed.

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Use of extractive distillation to produce concentrated nitric acid

Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub ...

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Understanding the 3 Different Nitric Acid Production Processes

As a result, three distinct processes have been developed for carrying out the various reactions. 1. Mono Medium Pressure Process. Using an uncooled radial compressor to deliver air at 4 to 5 bar abs or an axial flow compressor (5 to 6 bar abs) a nitric acid plant can produce up to 700 tons of nitric acid per day (maximum 65 percent ...

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Corrosion studies of stainless steel 304 L in nitric acid in the

In order to better understand the role of uranium on the corrosion behavior of stainless in aqueous nuclear fuel reprocessing and decontamination operations, 304L stainless steel coupons were treated with nitric acid media at 45 °C and 90 °C in the presence of 0.3 M of uranyl nitrate. The impact of time, temperature, nitric acid …

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NITRIC ACID MANUFACTURE

gases exhausted from a 55-ton nitric acid plant approximates 4500 cfm. The stack gases may contain 0.2 to 0.4% (vol) oxides of nitrogen expressed as nitrogen dioxide. The concentration of nitric acid by distillation with sulfuric acid does not involve an absorption reaction as does the ammonia oxidation process. The nitric acid concentration ...

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Direct Analysis of Trace Metal Impurities in High Purity Nitric …

Nitric acid (HNO 3) plays an important role in the fabrication of semiconductor devices so needs to be of ultrahigh purity. A mix of nitric and hydrofluoric acid is used to etch single crystal silicon and polycrystalline silicon. HNO 3 is also combined with phosphoric acid and acetic acid for wet etching of aluminum. As a reagent, HNO 3 is used ...

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Nitric Acid Prices, News, Monitor | ChemAnalyst

The prices of Nitric acid declined throughout the second quarter ending June 2023. The prices showed a dip of around 8.8% in the UK. Natural Gas and Ammonia, which are important inputs in the production of Nitric Acid, were both declining, which may be the cause of the decline in Nitric Acid prices. Further low procurement orders for …

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Nitric Acid Treatment | De Dietrich Process Systems

The majority of this nitric acid is used for the production of fertilizers. Other processes such as the production of explosives, pigments, rocket fuels or polyurethanes require higher concentrated nitric acid. For the …

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Nitric Acid Plants (PDF)

The basic process technology for producing nitric acid has not changed significantly over time. Most US plants were built between 1960 and 2000. There are presently 40 active weak nitric acid production plants and one high-strength nitric acid production plant. These plants are listed in Appendix B.

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Behaviour of ruthenium in nitric media (HLLW) in reprocessing plants…

General information on nitric acid solution. In aqueous solutions, nitric acid HNO 3 is a strong acid completely dissociated into H + ions and NO 3 − nitrate ions (for acidities below 2–3 M) and a powerful oxidant. Under the action of light and heat, various degradation products of nitric acid can be formed: nitrogenous derivatives of HNO 3, …

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8.8 Nitric Acid

8.8 Nitric Acid 8.8.1 General 1-2 In 1991, there were approximately 65 nitric acid (HNO 3) manufacturing plants in the U. S. with a total capacity of 11 million tons of HNO 3 per year. The plants range in size from 6,000 to 700,000 tons per year. About 70 percent of the nitric acid produced is consumed as an intermediate in the manufacture of

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Two-Stage Catalytic Abatement of N2O Emission in Nitric Acid Plants

Different variants for abatement of N2O emission from nitric acid plants with the use of catalysts developed at Łukasiewicz-INS were analyzed. Activity tests on a pilot scale confirmed the high activity of the studied catalysts. A two-stage catalytic abatement of N2O emission in nitric acid plants was proposed: by high-temperature …

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Conventional and advanced exergoeconomic indicators …

An advanced exergetic analysis is applied to a nitric acid production plant with a capacity to process 350 tons/day with a concentration of 55 %. Where catalytic oxidation of ammonia, condensation, and absorption of nitrous gases are considered the primary process in nitric acid production.

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Evaluation of hydroxamic acid in uranium extraction process

Composition and properties of the extractant and process chemistry are based on 30 vol% TRPO-kerosene as solvent. Hexa- and tetravalent actinides are highly extractable in 30 vol% TRPO extraction from acidic HAW, and trivalent americium (curium) can be extracted effectively from HAW with a nitric acid concentration of …

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OVERVIEW OF PRODUCTION OF NITRIC ACID

2005). Nitric acid is considered as the most powerful oxidizing agent that reacts violently by many organic materials. Their oxidation depends upon the acid concentration, temperature and reducing agents (Harold F, 2015). Hereby, by observing the growing importance of nitric acid, the production of nitric acid requires a

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Nitric Acid

3.3.12.1 Nitric Acid. Nitric acid (HNO3, also known as aqua fortis and spirit of niter) is a highly corrosive mineral acid. The pure compound is colorless, but older samples tend to acquire a yellow cast due to decomposition into nitrogen oxides (NO x) and water. Most commercially available nitric acid has a concentration of 68% (v/v) in water.

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KBR's MAGNAC High-Concentration Nitric Acid …

MAGNAC is used to produce 98.5 wt% high-concentration nitric acid from fresh, weak nitric acid. KBR's proven process and patented, unique equipment design and material selection ensure plant availability and reliability to deliver a high-value product …

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Process Analysis and Plant Design for Manufacturing of …

chemical plant for the production of nitric acid by ammonia oxidation process. Firstly, the description ... derivatives into nitric acid by spraying water from top of the column. The product obtained from absorption system is 57 to 60% concentrated. To increase its concentration level the product is recirculated to absorption system. III ...

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Modeling, simulation and optimization: Mono pressure nitric acid

The present work focuses on a strategy for optimizing mono pressure weak nitric acid plants. The optimization strategy addresses important processes which include oxidation of ammonia to nitric oxide, heat recovery from product stream of ammonia oxidation reactor and absorption accompanied by complex chemical reactions of multi …

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Modeling, simulation and optimization: Mono pressure …

The present work focuses on a strategy for optimizing mono pressure weak nitric acid plants. The optimization strategy addresses important processes which include oxidation of ammonia to nitric oxide, heat recovery from product stream of ammonia oxidation reactor and absorption accompanied by complex chemical reactions of multi …

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