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The role of aluminium in alkali-activated bentonites

The results show that the cleaning solution has a high potential to be used as an activator in the manufacturing of alkali activated cement, especially due to its …

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Rheological Properties of Alkali Activation Iraqi bentonite

Results show that effective viscosity increased by the effect of activation and the best results of effective viscosity of bentonite was taken from the combined alkali and acid activation...

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Alkali activation behaviour of un-calcined montmorillonite and illite

Although it has a similar Si:Al ratio, alkali activation of illite seems to result in structural alteration and increased porosity for Na:Al ≥ 0.5. The behaviour of these individual clay minerals suggests that the alkali activation of un-calcined 2:1 clay minerals is complex. Although alkali activation of montmorillonite can form a geopolymer ...

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The role of aluminium in alkali-activated bentonites

The third reaction raised the solution pH, which in turn hastened dehydroxylated bentonite dissolution, favouring its alkaline activation and the formation of N-A-S-H-like gels [14] (or (N,C)-A-S ...

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US3909454A

A method for activation of bentonites is described. The method comprises a prior treatment of the bentonite with an organic polymer and/or an aqueous alkaline solution as known from prior art. Subsequently, an amount of 0.01 - 10% by weight from the treated bentonite of a heavy metal salt is incorporated into the pretreated bentonite and then …

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Zeolite synthesis from industrial wastes

The characterization of the waste zeolites synthesized by alkali activation and hydrothermal method shows that the amount of Si and Al dissolved from glass, quartz and mullite are 50%, 2% and 2%, respectively. ... 65 °C, 72 h. The natural clays kaolinite, bentonite and feldspar, the synthesized zeolites 13X–K, 13X–B and 13X–F, and the ...

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Adsorption performance of phosphate in water by mixed …

The FA + MK-0.8 prepared in this study had the maximum removal efficiency of 94.21% for phosphate in water with a maximum adsorption capacity of 36.02 mg/kg. The alkali activation process destroyed the mineral structure of the material, increased the adsorption sites on the surface of the geopolymer, and accelerated phosphate …

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Synthesis and Characterization of High-Performance Blended Alkali

By calcining poor-quality bentonite with Na 2 CO 3 and dolomite, one-part alkali-activated cements (AACs) were produced. The alkali addition enhances the phase composition of the clinkers and makes hydration easier, which boosts the cementing activity under the suitable chemical circumstances and tolerable calcination settings (Peng et al. …

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Synthesis of Zeolite of Type A from Bentonite by Alkali Fusion

Ma et al., (2010) performed zeolite A synthesis from bentonite via alkali fusion-assisted hydrothermal method (Ma et al., 2010). A mixture of Al(OH) 3, Na 2 CO 3 and bentonite was fused at 830 ...

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The role of aluminium in alkali-activated bentonites

Bentonites. Alkali activation. Bauxite. (SiO 2 /Al 2 O 3) reactive. In the pursuit of new sources of aluminosilicates for alkaline cement manufacture, the present paper reports on the compositional and mineralogical assessment of the reactive potential of several types of bentonites.

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XRD patterns of bentonite and heat-treated bentonite.

Download scientific diagram | XRD patterns of bentonite and heat-treated bentonite. from publication: Synthesis of Zeolite of Type A from Bentonite by Alkali Fusion Activation Using Na 2 CO 3 ...

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Fly ash-based geopolymers: an emerging sustainable

Alkali activation is a typical chemical treatment for fly ash that is used in a variety of applications. ... A plot of log Q e versus log C e would result in a straight line with a slope of (1/n) and intercept of ... (2017) A comprehensive review on recent developments in bentonite-based materials used as adsorbents for wastewater treatment. J ...

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Spent bleaching earth; recycling and utilization techniques: A review

Although thermal-activation of bentonite is a straightforward process, a proper activation temperature is needed to retain the layers' structure and maintain the active adsorption sites of the bleaching bentonite clay. ... Besides, SBE was effectively transformed into silica adsorbents by the alkali activation method. It was found that …

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Preparation of high-strength ceramsite from red mud, fly ash, and bentonite

Bentonite was purchased from Shanghai Macklin Co., Ltd. Ultrapure water and deionised water were obtained from a lab pure water system (Ultra Pure, Hitech). Because RM contains a low amount of silicon and aluminium, fly ash was added to increase SiO 2 and Al 2 O 3 contents and ensure the formation of sufficient liquid phase to obtain a …

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Minerals | Free Full-Text | Hybrid Alkaline Cements: Bentonite

Moderately alkaline activators can be used to formulate cementitious binders with a high Supplemetary Cementitious Materials (SCMs) and a low portland cement content (hybrid alkaline cements). This study aimed to prepare hybrid alkaline cements containing large percentages of dehydroxylated bentonite (BT) and small Portland cement (OPC) …

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Bentonites

Use of bentonite for soil improvement. Instead of grass, fresh grains and field crops increasingly prepared feed is fed to farm animals. Bentonite is a versatile natural product, which contributes to improve quality of life in many areas . Frequently animal feed is mould infested with so-called mycotoxins releasing dangerous toxic substances.

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The role of aluminium in alkali-activated bentonites

The findings showed that de-hydroxylated bentonite reacted with an alkaline activator, yielding materials with cementitious properties. The addition of 10 % sodium …

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Activation of (Na, Ca)-bentonites with soda and MgO and their

Activation of these shales was performed using the most popular (Na 2 CO 3), carboxy-methylcellulose, and polymers. The drilling mud qualities of the shales from Wadi El Natrun were significantly improved with additives and upgraded to have rheological properties compatible with American Petroleum Institute and Oil Companies Material ...

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Rehydration Driven Na-Activation of Bentonite—Evolution of the …

A new method of Na-activation of raw bentonite, rich in Ca-montmorillonite, consisting of combined thermal treatment at 200 °C, followed by immediate impregnation with aqueous solution of Na 2 CO 3 of concentration corresponding to 0.5, 1.0, 1.5, or 2.0 cation exchange capacity (CEC) of clay, was investigated. Structural and compositional evolution of the …

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(PDF) Investigation of Used Motor Oil Regeneration

Goshica's (Kosovo) bentonite was activated with three activation methods, namely, acid, alkaline and combined acid-alkaline activation, and their regeneration efficiency of used motor oil (UMO ...

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Advances in alkali-activation of clay minerals

The primary reaction products of alkali-activation of low-Ca precursors, such as clay minerals, are alkali aluminosilicates – these are classified as either crystalline zeolitic phases, or sodium aluminosilicate hydrates (N-A-S-H) gel frameworks. ... The term bentonite has been avoided here, as it is a commercial name than can refer to a ...

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Frontiers | Silico-Aluminophosphate and Alkali-Aluminosilicate

where n is the degree of geopolymerization, z is 1, 2, or 3, and M is an alkali cation (e.g., K or Na).. Recently, the term "chemically-activated materials" (CAMs) was also proposed to describe the aluminosilicate sources that can be activated to create cementitious matrices using some chemical solutions (e.g., alkali-silicate, phosphate and other chemicals) …

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Characterization of activated bentonite clay mineral and …

After the acid activation, the analysis data showed a significant change in the chemical composition in modified bentonite clay, compared to the raw bentonite …

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Frontiers | Potential of Acid-Activated Bentonite and SO3H

Application of acid-activated bentonite and SO3H-functionlized multiwall carbon nanotubes (SO3H-MWCNTs) for lowering free fatty acids (FFAs) content of low-quality residual olive oil, prior to alkali-catalyzed transesterification was investigated. The used bentonite was first characterized by Scanning Electron Microscopy (SEM), …

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Role of Natural Stone Wastes and Minerals in the Alkali Activation

This review aims to provide a comprehensive assessment concerning alkali activation of natural stone wastes and minerals. In particular, the structure of the review is divided into two main sections in which the works dealing with alumino-silicate and carbonatic stones are discussed, respectively. Alumino-silicate stones are generally …

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Physico-chemical characterization of thermally treated bentonite

As a possible consequence of the increased openness could be the acceleration of alkali-activation process resulting, for example, in the acceleration of the strength development of binding system based on the thermally treated bentonite. ... Activation of Iraqi bentonite – part II: thermal activation. Can J Chem Eng Technol (3) …

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Minerals | Free Full-Text | Hybrid Alkaline Cements: …

Download. Browse Figures. Versions Notes. Abstract. Moderately alkaline activators can be used to formulate cementitious binders with a high Supplemetary …

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Fresh mechanical and durability properties of alkali

This paper describes a review of the state-of-the-art research carried on the fresh and hardened properties of Alkali Activated Binders and Concretes. Though, many research have been carried out in the recent times on alkali activated binders, few key parameters still remain unattended, that restricts the commercial application of AAMs to …

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Simultaneous thermal analysis of different bentonite–sodium …

Alkali activation with sodium carbonates is a traditional method to improve bentonite properties for a variety of applications. In some applications, natural sodium-rich bentonites are preferred, and custom regulations require proper declaration of Na-rich bentonites, with respect to activation.

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Processing Of Activation Bentonite

Bentonite production line – Crusher Bentonite processing… the crude bentonite … sodium activated bentonite process – Basalt Crusher Bentonite Process Plant CQC: ISO9001:2000 Brand Name: Binq Place of Origin: …

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One step acid activation of bentonite derived adsorbent …

Herein, the facile one step acid activation of bentonite derived functionalized adsorbent (AB) for the effective remediation of both ionic and non-ionic …

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Synthesis and Characterization of Fly Ash-Based Geopolymers

The spent caustic with strong alkali first replaced the alkali activator to prepare the geopolymer. The influence of spent caustic to the geopolymer was characterized through compressive strength measurement, XRD, MIP analysis and NMR, and the immobilization efficiency of organic in geopolymer was evaluated through the …

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Synthesis, characterization and mechanisms of one-part

Na 2 SiO 3, Na 2 Al 2 O 4 and Na 2 Al 2 Si 2 O 9 were found in the bentonite through alkali fusion activation using Na 2 CO 3 at 830 °C, and zeolite of type A was produced during the following hydration process of the treated bentonite in water at 90 °C for 6 h. The thermally treated albite with alkali also generated zeolite when hydrated .

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(PDF) Bentonite processing

The bentonite beneficiation were carried out in two stages [9]; samples were milled, screened, washed with distilled water and dried at …

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Method of activating bentonite clays

The time of activation lasted 3 hours after which the material was directed to a suitable drier. Average of three tests on the raw material: R -0.86 kg./cm. ... In a method of activating bentonite clay with an alkali activator solution, an improvement comprising applying the solution to the clay prior to mechanical working of the same to retain ...

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Metabentonite and metakaolin-based geopolymers/zeolites: …

Alkali-activated binders or geopolymers are materials formed from a mixture of an aluminosilicate material with media solutions such as NaOH, sodium or potassium silicate, and phosphoric acid.[1, 2].While metakaolin (MK) is generally very often used as supplementary cementitious materials [3,4,5,6] as well as for geopolymers or zeolites …

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Alkaline Activation

An overview of the chemistry of alkali-activated cement-based binders. I. Garcia-Lodeiro, ... A. Fernández-Jiménez, in Handbook of Alkali-Activated Cements, Mortars and …

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Formation mechanism of carbide slag composite sustained

According to Provis et al. 40, the formation of C–S–H, C–A–H, and C–A–S–H gels depends on the activation of alkali metal hydroxides or carbonates (i.e., Na 2 CO 3). Increasing the ...

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Microstructure and mechanical performance of alkali-activated tuff

The sum of SiO 2 (69.9%), Al 2 O 3 (11.5%), and Fe 2 O 3 (1.6%) in the tuff powder exceeds 80%, indicating its potential for alkali activation [34]. The contents of CaO and MgO in GGBS are 33.9 and 10.6% respectively, which are normally used as supplemental calcium and magnesium in the cement industry [35, 36].

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Bentonite transformations in strongly alkaline solutions

For alkali activation, both raw and calcined clays with varying degrees of effectiveness can be used. ... whereas the low-pH concrete solution did not reduce the swelling capacity of bentonite ...

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