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Ultra-fine grinding and mechanical activation of mine waste rock …

The CO 2 sequestration conversion of mechanically-activated olivine and mine waste are 22.5% and 31.5%, respectively, with 3600 kWh/t specific milling energy input after one hour direct aqueous carbonation. For the purposes of mineral carbonation, the mechanical activation of mine waste is preferable to simply grinding pure olivine.

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Low‐Temperature Plasticity in Olivine: Grain Size, Strain …

Key Points. D-DIA experiments were conducted on stacked samples of olivine, allowing precise determination of yield strength and subsequent hardening. …

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Transformation of abundant magnesium silicate minerals for

The total energy required, including quarrying and grinding, to produce Mg(OH) 2 from olivine was calculated to be 6.28 GJ tonne −1 (see Fig. 1 and Supplementary Methods for energy ...

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Carbon Dioxide Sequestration by Direct Mineral Carbonation: …

Direct aqueous mineral carbonation has been investigated as a process to convert gaseous CO2 into a geologically stable, solid final form. The process utilizes a solution of distilled water, or sodium bicarbonate (NaHCO3), sodium chloride (NaCl), and water, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine …

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Olivine: a supergreen fuel

The hydration and carbonation of olivine, the most common mineral on Earth, produce a large amount of heat. Unfortunately, the reaction is too slow for normal technological applications, but when thermally well isolated, most of this heat can be recovered, not only for space heating but even for the production of high-pressure steam. …

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Mechanical activation of olivine

This paper investigates how mechanical activation of olivine can increase the mineral's surface reactivity, and illustrates how such technology can give rise to new or improved olivine products. The olivine material used in this study consisted of pure olivine crystals (Mg 1.860 Fe 0.134 Ni 0.006 SiO 4 ) originating from North Cape Minerals ...

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Frontiers | The Dissolution of Olivine Added to Soil at …

Crushed olivine was added to a soil core to mimic enhanced weathering, and water was continually dripped through for ~6 months. Our experiments were conducted at 4°C, and are compared to previously run …

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Potential and costs of carbon dioxide removal by enhanced

The natural weathering process can be enhanced by grinding selected rocks to small grain sizes to increase the specific surface area, ... which mainly bears fast-weathering forsteritic olivine. ... which may affect overall dissolution kinetics due to changes in hydrological flow path and residence time. 2.

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Laboratory investigation of mechanisms for phase mixing …

Abstract. To investigate the role of grain boundary pinning and the mechanisms by which phase mixing occurs during deformation of …

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Olivine Dissolution in Seawater: Implications for CO2 …

Enhanced weathering of (ultra)basic silicate rocks such as olivine-rich dunite has been proposed as a large-scale climate engineering approach. When implemented in coastal environments, olivine weathering is expected to increase seawater alkalinity, thus resulting in additional CO2 uptake from the atmosphere. However, the mechanisms of marine …

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Bond Work Index Formula-Equation

where W is the work input required in kilowatt hours per short ton to grind from 80% passing F microns to 80% passing P microns, and Wi is the work index, or the grinding resistance parameter. It represents the energy input required in kilowatt hours to reduce a short ton from theoretically infinite feed size to 80% passing 100 microns.

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Low‐Temperature Plasticity in Olivine: Grain Size, Strain Hardening

Some authors have calibrated steady state flow laws for olivine plasticity using stresses measured at strains greater than 5–20%, that is, ... For both starting and deformed samples, material was impregnated with epoxy resin and then ground using a diamond grinding wheel. Ground surfaces were then polished with diamond slurries of ...

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Geoengineering potential of artificially enhanced silicate

The net CO 2 sequestration efficiency will be reduced by 5–10% because of CO 2 emissions by mining and grinding of olivine . The less energy-demanding grinding to a 37-μm size would cause only a decrease of the net efficiency by 0.7–1.5% because of differences in grinding techniques ( 22 ) but may not be sufficient for the attempted fast ...

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Diffusion creep of dry, melt-free olivine

[1] Deformation experiments were conducted on fine-grained (3–6 μm), fully synthetic Fo 90 olivine aggregates in a gas-medium apparatus at 300 MPa confining pressure and temperatures of 1150–1360°C. The strain rates of the solution-gelation-derived and therefore genuinely melt-free, dry samples are about two orders of magnitude lower …

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EGUsphere

Abstract. Ocean alkalinity enhancement (OAE) aims to increase atmospheric CO 2 sequestration in the oceans through the acceleration of chemical rock weathering. This could be achieved by grinding rocks containing alkaline minerals and adding the rock powder to the surface ocean where it dissolves and chemically locks CO 2 in seawater …

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Low-temperature plasticity of olivine revisited with in situ TEM

The rheology of the lithospheric mantle is fundamental to understanding how mantle convection couples with plate tectonics ().There is a growing consensus that the rheology of olivine at low temperatures relevant for the lithospheric mantle cannot be extrapolated from rheological laws established from experiments at high temperature (ca. …

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Mechanical activation of olivine

Abstract. This paper investigates how mechanical activation of olivine can increase the mineral's surface reactivity, and illustrates how such technology can give …

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The role of the antigorite + brucite to olivine reaction in subducted

Metamorphic olivine formed by the reaction of antigorite + brucite is widespread in serpentinites that crop out in glacier-polished outcrops at the Unterer Theodulglacier, Zermatt. Olivine overgrows a relic magnetite mesh texture formed during ocean floor serpentinization. Serpentinization is associated with rodingitisation of mafic …

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Surface characterization of ash-layered olivine from fluidized bed

2.1 Description of the industrial DFB gasification plant in Senden. Bed material samples for used layered olivine were taken from the industrial-scale DFB gasification plant in Senden, Germany. The power plant has a fuel power of 15 MW th and generates electricity of about 5.1 MW el by means of two gas engines and an organic rankine cycle …

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Kinetic evaluation of mineral carbonation of natural

Olivine dissolution was the rate controlling step during natural silicate carbonation. ... Proposed engineering flow diagram of Turnagain mine, Giga Metals Corporation. ... The P 80 of particles after grinding is around 85 µm. Since the target mineral is naturally hydrophobic, there is no need to add sulfide reagents (e.g. NaHS) …

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Carbon dioxide sequestration by direct mineral carbonation with

The ARC tests have focused on ex-situ mineral carbonation in an aqueous system. The process developed at ARC utilizes a slurry of water mixed with a magnesium silicate mineral, olivine [forsterite end member (Mg2SiO4)], or serpentine [Mg3Si2O5(OH)4]. This slurry is reacted with supercritical carbon dioxide (CO2) to …

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Grinding methods to enhance the reactivity of olivine

Activated olivine is one of several solid feed materials used at ARC in reactions with carbon dioxide toform carbonate minerals. This paper compares grinding …

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Aqueous Mineral Carbonation: Mineral Availability, Pretreatment

Research has shown that the carbonation of serpentine is 10-fold slower or more than olivine if not exposed to >600 • C prior to carbonation (Gerdemann et al., 2007;Kelemen et al., 2011; Oconnor ...

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Engineered carbon mineralization in ultramafic rocks for CO2

These reactions are spontaneous and exothermic; carbonate minerals are the "ground state" for CO 2 in near-surface rock systems such as Mg-Ca-C-O-H and Mg-Ca-Si-C-O-H (Fig. 1).The energy density of unreacted olivine in the presence of H 2 O or CO 2 at low temperature is ~2 GJ/m 3, only ~20 times smaller than the energy density of …

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Unveiling redox mechanism at the iron centers in the

As a first experiment, the wet olivine powders were exposed to a carbon dioxide flow (10 ml/min) into a static reactor for 60 min, and no conversion was observed by GC analysis. Similarly, negligible amounts of hydrogen and methane were recorded when the pristine powders were subjected to simply agitation at 875 rpm without grinding …

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Re-carbonizing the sea: Scientists to start testing a big ocean …

Olivine is a volcanic mineral which, when introduced to the ocean, disintegrates and chemically transforms, making that part of the ocean a little more alkaline and securely storing dissolved CO 2 ...

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Synthesis of Nanosilica via Olivine Mineral Carbonation under High

Synthesis of nanosilica was studie d via carbonation of olivine using size fraction between 20 and. 63µm with solid/liquid ratios of 1:10 at 175 °C and partial pressure of CO 2 more than 100 bar ...

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Enhanced chemical weathering as a geoengineering …

For example, using the energy consumption described by equation (9), the net CO 2 sequestration efficiency of olivine application to soils would be reduced by 5%–10% because of CO 2 emissions related to the mining …

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Stress-induced amorphization triggers deformation in the …

Once the glass transition temperature of olivine glass is reached, amorphized grain boundaries flow, which enhances sliding and leads to a marked decrease in the viscosity of the mantle rocks.

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Calorimetric measurements of fusion enthalpies for Ni2

Calorimetric measurements of fusion enthalpies for Ni 2 SiO 4 and Co 2 SiO 4 olivines were carried out using a high-temperature calorimeter, and Ni and Co partitioning between olivine and silicate liquid was analyzed using the measured heats of fusion. The fusion enthalpy of Co 2 SiO 4 olivine measured by transposed-temperature …

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Grinding methods to enhance the reactivity of olivine

impact on reactivity, and wet grinding is more energy efficient than dry grinding. Large additional inputs of energy to increase surface area or reduce crystallinity do not result in …

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Oxidation during magma mixing recorded by symplectites

Kusatsu–Shirane Volcano is an active Quaternary andesitic-to-dacitic volcano located in the Central Japan Arc. We conducted a detailed petrological investigation of orthopyroxene (opx)–magnetite (mt) symplectites associated with olivine in the Sessho lava, an andesitic lava flow from Kusatsu–Shirane. We concluded that the symplectites …

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Structural and chemical changes in mine waste

Sandivik et al. has compared the mechanical activation effects of olivine under various grinding modes, include wet, moisture (10 wt% H 2 O), dry modes. They found that grinding under wet conditions typically produces finer particle sizes and larger surface areas than dry grinding at the same energy input.

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