ball milled mgh2 5 wt mm fe and fef3 nanocomposites for improving hydrogen storage
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- ball milled mgh2 5 wt mm fe and fef3 nanocomposites for improving hydrogen storage
Magnesium hydride ball milled nanocomposites was prepared separately using vibratory and planetary ball milling devices under argon atmosphere, mixing with 5%wt. Fe and …
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In the present investigation, we have reported the synergistic effect of Fe nanoparticles and hollow carbon spheres composite on the hydrogen storage properties of MgH 2.The onset desorption temperature for MgH 2 catalyzed with hollow carbon spheres and Fe nanoparticle (MgH 2-Fe-HCS) system has been observed to be 225.9 °C with a …
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In this formula, P 0 is the atmospheric pressure (1.01 × 10 5 Pa); ∆H and ∆S are the enthalpy and entropy of the hydrogen ab/de-sorption, respectively; and T is the absolute temperature; R is the gas constant (R = 8.314 J mol −1 K −1).According to the linear fitting between lnP and 1000/T, ∆H and ∆S can be calculated. Notably, the value of …
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High energy vibrational ball milling device was used under argon atmosphere to prepare two series of nanocomposite of MgH2 with 5%wt. M (M= Fe, …
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Among the metal hydrides, MgH 2 is still one of the most attractive candidates for hydrogen storage due to its high theoretical gravimetric capacity of 7.6 wt.%, volumetric capacity of 110 g L −1, energy density of 9 MJ kg −1, abundance, reversibility and low cost [2]. Moreover, MgH 2 possesses other advantages, such as heat-resistance ...
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The nanocomposite MgH2/10 wt.% and 15 wt.% Nb2O5 exhibit good hydrogen storage capabilities at a comparatively low temperature (225 °C) with a long cycle life that extended from 110 h to 170 h ...
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The capability of hydrogen uptake and release for the as-synthesized nanocomposite MgH 2 /5.3 wt% TiH 2 powder was examined at a relatively low …
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Herein, it is confirmed that MnMoO 4 rod catalyst can effectively improve the hydrogen storage performance of MgH 2. According to the experimental results, MgH 2 +10 wt%MnMoO 4 composite material starts dehydrogenation at about 220 °C, which is about 140 °C lower than MgH 2 without additives. The initial dehydrogenation capacity of …
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MgH2+20 wt.% LiFePO4 obtained by ball-milling process had an ability of absorbing 2.03 wt.% hydrogen at 423 K in 21 min, and only 0.98 wt.% could be absorbed by MgH2 for the identical condition. 3 ...
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The prepared nanocrystalline TiO 2 @C was then introduced into MgH 2, and five composites with compositions of MgH 2-x wt% TiO 2 @C (x = 0, 5, 7, 10, and 12) were prepared to evaluate its catalytic effect on the hydrogen storage reaction of MgH 2. Fig. 2 (a) shows the XRD patterns of the milled MgH 2-x wt% TiO 2 @C samples. As …
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Based on, Mg hydride is the most promising material to store hydrogen in a solid-state material. The theoretical hydrogen storage capacity of magnesium hydride is 7.6 wt% making it a more suitable material for hydrogen storage in the future. Instead of having high storage capacity, magnesium's practical application as a hydride is limited …
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Herein, MgH2 − x wt% MM (x = 0, 10, 20, 30) nanomaterials are prepared via ball milling method and has been evaluated for the hydrogen storage performance, which are characterized by XRD, SEM ...
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The study used ball-milling to create composites of Mg 90 Ce 5 Y 5 with various amounts of Dy 2 O 3 catalyst (0, 2, 4, 6, 8 wt. %). The structures of samples were analyzed and it was found that the hydrogen storage mechanism involved the reactions: Mg + H 2 ↔ MgH 2 and DyH 2 + H 2 ↔ DyH 3, and the stable phases CeO 2, YH 2, and …
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High energy vibrational ball milling device was used under argon atmosphere to prepare two series of nanocomposite of MgH2 with 5%wt. M (M= Fe, FeF3 and VF3) …
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Therefore, this paper will report the results of a study on MgH 2 -based hydrogen storage materials with Fe 2 O 3 catalyst inserted (5 wt%, 10 wt%, 15wt%) and prepared by mechanical alloying ...
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Mn nanoparticles (nano-Mn) were successfully synthesized and doped into MgH 2 to improve its de/hydrogenation properties. Compared with MgH 2, the onset desorption temperature of 10 wt.% nano-Mn modified MgH 2 was decreased to 175 °C and 6.7, 6.5 and 6.1 wt.% hydrogen could be released within 5, 10 and 25 min at 300, 275 …
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High energy vibrational ball milling device was used under argon atmosphere to prepare two series of nanocomposite of MgH2 with 5%wt. M ( M = Fe, FeF3 and VF3) in order …
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Sadhasivam et al. [34] achieved a decrease in the onset desorption temperature from 381 °C (ball-milled) to 305 °C, viz. a decrease by 76 °C, by introducing 5 wt% Mm-oxide to MgH2. Show abstract Nano-rare earth hydrides generated in situ were believed to catalyze the reversible reaction of magnesium-based alloys and hydrogen.
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Magnesium hydride ball milled nanocomposites was prepared separately using vibratory and planetary ball milling devices under argon atmosphere, mixing with …
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This composition absorbed 7.2 wt % hydrogen within 5 min at 200 °C and 5.5 wt % at 30 °C within 2 h, while the desorption capacity (6.0 wt %) was measured at 275 °C within 7 min.
به خواندن ادامه دهیدIn this study, the hydrogen storage properties of MgH2 with the addition of K2TiF6 were investigated for the first time. The temperature-programmed desorption results showed that the addition of 10 wt% K2TiF6 to the MgH2 exhibited a lower onset desorption temperature of 245 °C, which was a decrease of about 105 °C and 205 °C compared with the as …
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A study of the effect of the ball-milling gas environment on the kinetic enhancement of MgH 2 with different additives was conducted using argon and hydrogen. The as-sourced MgH 2 was milled for 20 h and then milled for a further 2 h after adding 1–2 mol% of one of the additives titanium isopropoxide, niobium oxide or carbon buckyballs, …
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Magnesium hydride ball milled nanocomposites was prepared separately using vibratory and planetary ball milling devices under argon atmosphere, mixing with 5%wt. Fe and FeF 3 to improve the kinetics of H-sorption without reducing the high hydrogen storage capacity. Morphology, structural and thermal characterization of the MgH 2 composites …
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A synergetic catalytic effect of Ti, Fe and Ni on hydrogen desorption have been observed in the ball milled MgH 2 –Ti 5 Fe 5 Ni 5 nanocomposite [20]. This material desorbed hydrogen at the temperature by 30–60 °C lower than nano MgH 2 catalyzed separately with Ti, Fe and Ni. The effect of FeTi alloy and elemental Ti and Fe on the ...
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Abstract: Magnesium hydride ball milled nanocomposites was prepared separately using vibratory and planetary ball milling devices under argon atmosphere, mixing with 5%wt. Fe and FeF 3 to improve the kinetics of H-sorption without reducing the high hydrogen storage capacity. Morphology, structural and thermal characterization of the MgH 2 …
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Ball Milled MgH2+5%wt. M (M = Fe and FeF3) Nanocomposites For Improving Hydrogen Storage. ... mixing with 5%wt. Fe and FeF3 to improve the kinetics of H-sorption without reducing the high hydrogen ...
به خواندن ادامه دهیدIn the field of energy storage, recently investigated nanocomposites show promise in terms of high hydrogen uptake and release with enhancement in the reaction kinetics. Among several, carbonaceous nanovariants like carbon nanotubes (CNTs), fullerenes, and graphitic nanofibers reveal reversible hydrogen sorption characteristics …
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Similarly to the Mg–Fe system, reactive ball-milling of Mg and Co under hydrogen gas led to the formation of Mg 2 CoH 5 with the gravimetric storage capacity of 4.5 wt%, hydride formation enthalpy of −82 kJ mol −1 H 2 and desorption temperature for 1 bar hydrogen pressure of about 513 K. 37 It is important to highlight that the formation ...
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Recently, Attia et al. attained a maximum hydrogen storage capacity of 0.78 wt% at room temperature and 0.5 MPa for PANI/HNT ball-milled nanocomposites . A 3.67 wt% hydrogen storage capacity was obtained at 100 bar and − 193 °C for PANI BF 3 + 10%SWCNT nanocomposite . Donya et al. obtained a maximum hydrogen storage …
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