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Cement hydration mechanisms through time – a review

Based on our current knowledge of cement hydration, many of the findings of Le Chatelier [10, 11] were accurate, especially his investigations of the clinker chemistry were later confirmed by other authors [15, 17, 25].In particular, the petrographic study of Törnebohm [] shall be mentioned here since the major clinker phases Alite and Belite …

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Clinker Liquid Phase | PDF

5.CONCLUSIONS Although the amount of liquid phase in the burning and transition zones of the kiln is important to clinker formation and brick performance, the rheological properties of the melt are even more important. The rheological properties of the clinker melt control parameters such as clinker mineral formation, clinker coatability, …

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An Insight into the Chemistry of Cement—A Review

Even if cement is a well-consolidated material, the chemistry of cement (and the chemistry inside cement) remains very complex and still non-obvious. What is sure is that the hydration mechanism plays a pivotal role in the development of cements with specific final chemical compositions, mechanical properties, and porosities. This …

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Modeling of cement clinker chemistry and engineering of …

Abstract. The purpose of this article is to review the aspects related to cement chemistry, more particularly to the process of clinkerization in the cement rotary kiln. …

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Influence of Corrective and Additive Raw Materials on Clinker

Since the clinker phase texture gives useful information about the raw materials used and the manufacture process, the clinker phase types and their microstructures were determined using Bogue equations, XRD, SEM and EDAX techniques. ... Phases abundance estimates are commonly derived from the bulk chemistry using …

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Co-firing of Alternative Fuels in Cement Kiln Burners

The model describes and links together the fuel combustion, gas mixing, heat transfer, and clinker chemistry. The model calculates temperatures in the gas phase and clinker bed through the kiln and the clinker composition is given as output. Thus, the impacts of co-firing different alternative fuels can be studied.

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Microstructure and Properties of Sulfoaluminate Cement-Based

Effect of calcium sulfate variety on the microstructure and properties of cement-based grouting materials made by sulfoaluminate cement clinker, calcium sulfate resource, and quicklime was investigated in this paper. Isothermal calorimetric, XRD, DTA-TG, and SEM-EDS were used to characterize the reaction process of cement-based …

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Alternative Fuels for use in Cement Kilns: Process Impact Modelling

Most of the studies on modeling cement manufacturing found in the literature are based on computational fluid dynamics (CFD) [8-13]. Kaantee et al. [6] and Zhang et al. [14] used Aspen Plus, a commercial software package, to simulate the cement clinker production focusing on clinker chemistry and thermodynamics in the rotary kiln.

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The chemistry of Portland cement clinker | Advances in Cement …

Source: Advances in Cement Research, Volume 2, Issue 6, 1 Apr 1989 (55–59) Technological developments in over a century of production of Portland cement clinker have greatly improved the homogeneity of the feed and clinker leading to much more favourable conditions for alite formation which remains the key chemical reaction in …

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Research review of cement clinker chemistry

This paper aims to review the progress in cement clinker chemistry since the last International Conference on the Chemistry of Cement in 2011. Although Portland …

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Clinker

Clinker. Clinker is the backbone of cement production. It is essentially a mix of limestone and minerals that have been heated in a kiln and have been transformed by this heat. When limestone is converted to clinker, CO 2 is released (also known as process emissions). A substantial amount of heat is needed to start and sustain the chemical ...

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Effects and Control of Chemical Composition of Clinker for …

1.1. Raw Feed Chemistry In order to achieved the required clinker chemical composition during sintering the raw feed chemistry must be set. Different chemical parameters can be used for controlled depends on the number of raw materials used to prepare the feed. Usually the number of target parameters which can be

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Clinker Production

Clinker Production - an overview | ScienceDirect Topics. The clinker production stage is where the raw material (the raw meal) converts into clinker. From: Journal of Cleaner …

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Effects and Control of Chemical Composition of Clinker for …

This research focused the role to study the effects and ways to control the chemical composition of clinker for better cement production. Cement is a substance produced by grinding a mixture of a ...

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Cement substitution with secondary materials can reduce annual …

On the other hand, secondary CMs, while also limited by the overall workability and chemistry of the cement system, frequently have small environmental impacts relative to clinker production, and ...

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Research review of cement clinker chemistry

This paper aims to review the progress in cement clinker chemistry since the last International Conference on the Chemistry of Cement in 2011. Although Portland cement clinker is still, by far, the most important compound of modern cements we show …

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Cement and Concrete Chemistry | SpringerLink

Complete description of clinker formation and cement production, including different types of binders. Richly annotated with 500 figures and diagrams to aid the understanding of complicated problems encountered by …

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Clinker Production

C. David Lawrence, in Lea's Chemistry of Cement and Concrete (Fourth Edition), 1998. Effect of proportions and activities of the main clinker minerals on water demand and fluidity. Slow cooling during clinker production results in an increased reactivity, due to the production of larger crystal sizes for C 3 A, and consequently larger water ...

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Screening Out Reactivity-Promoting Candidates for γ-Ca

Mu et al. (2019) found that the γ-Ca 2 SiO 4 samples exposed to a carbon dioxide environment under high pressure achieved mechanical properties in hours equivalent to that of the hydration product of a cement clinker hydrated for days, which provides a perspective of using carbonation-activated cementitious materials to reduce …

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Effect of iron on mineral composition of quaternary phase clinker …

The variation of clinker composition with Fe 2 O 3 dosage is shown in Fig. 3.In the figure, phase Q and CA are the major hydratable minerals, while MA and C 2 AS may be regarded as inert. The clinker R comprises primarily phase Q, as well as minor amounts of MA spinel. With the increase in the Fe 2 O 3 content, the quantities of C 4 AF and inert …

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(PDF) Comparing the effects of jouravskite and ettringite on the

chemistry of the clinker. This strategy was imple-mented in the early 1990s (2). Municipal, industri-al, and agricultural wastes are now largely used in . the cement plants. For the cement ...

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Phase Analysis of Portland Cement by Combined …

cement clinker was thought to be composed primarily of either a complex single compound containing lime, alumina, and silica, or separate silicate compounds containing varying amounts of lime. In their groundbreaking study, Brownmiller and Bogue compared X-ray diffraction patterns obtained from a

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Grinding aids for high performance cements

several parameters, ranging from clinker chemistry and reactivity to cement particle size distribution. The production of such high performing cements at a reasonable cost (from the point of view of clinker content and energy requirement for high fineness grinding) can be challenging and the use of suitable cement additives becomes mandatory.

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Cement and Concrete Chemistry | SpringerLink

This monograph describes cement clinker formation. It covers multicomponent systems, clinker phase structures and their reactions with water, hydrate composition and structure, as well as their physical …

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[PDF] MODELLING A CEMENT MANUFACTURING PROCESS …

It is also used to predict the possible changes in the combustion, precalcining and clinker formation processes. The waste tyre fuel for example also acts as a raw material in the clinker manufacturing process. Calculations with different descriptions of the clinker chemistry were made and evaluated against real process data where possible.

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Comparison of energy consumption and carbon emissions from clinker …

The conversion to energy consumed by amount of clinker was done based on the most recent data found concerning the average proportion of clinker in the cement. IEA, 2016, the clinker content on cement was 74% and 75% in the EU-28 (ATIC, 2019) and Portugal (ATIC, 2019), respectively. In 2014, it was 75% at world level (WBCSD, 2016).

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Modeling of cement clinker chemistry and engineering of cement

This paper aims to review the progress in cement clinker chemistry since the last International Conference on the Chemistry of Cement in 2011. Although Portland cement clinker is still, by far ...

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(PDF) An Insight into the Chemistry of Cement—A …

clinker minerals, producing Ca 2+, OH −, SO 4 2− ions, and ionic concentrat ion differences through steps in the liquid phase, and causing the supersaturation phenomenon necessary for the ...

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A machine learning approach for clinker quality prediction and

A cement plant of our industry partner is used in this study. As shown in Figure 1, the cement kiln takes the raw kiln feed and thermally transforms this into cement clinker.This process uses multiple heat exchangers represented by four main production zones: a 5-stage Single-String Preheater Tower, a PyroClon Calciner (Precalciner) and …

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HEAVY FUEL OIL COMBUSTION IN A CEMENT ROTARY KILN …

[16], heat transfer based on quasi-dynamic method in [17], and clinker chemistry presented in [14]. In the present study, the main work is to provide experimental data and to present a .

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Chemistry and engineering of the clinkerization process — …

Present perception of clinker chemistry and process technology. The major developments in cement chemistry in general and clinker manufacturing chemistry in particular over three decades from 1964 to 1989 can be perused in [1].

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The chemistry of Portland cement clinker | Advances in Cement …

Abstract. Technological developments in over a century of production of Portland cement clinker have greatly improved the homogeneity of the feed and clinker …

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Hydration and mixture design of calcined clay blended

The influence of clinker and limestone mineralogy are also discussed. Finally, guidelines for optimising the mixture design of calcined clay blended cements are provided, with special attention to sulphate adjustment and clinker factor. ... The chemistry of the reactive compound in the clay can be adjusted depending on the composition of the ...

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Chemistry and engineering of the clinkerization process …

"Chemistry" and "process engineering" constitute the foundation of the clinkerization process but over the decades the engineering advances have been …

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